Perhaps it had a problem and the previous owner just dumped some hardware store sealant crap in it. Try stopping by a radiator shop and asking, maybe a complete flush and then a pressure test. That would narrow down your options. If the head is cracked - you need a new one. If it was just a gasket leak that's a lot less than a new or rebuilt engine.
Oh yeah, Don't drive it. It will NOT get better and very bad and expensive things WILL happen.